Put into bat, the visitors made 216-5 in their 50 overs.
Akhil Patel (47) and George Bacon (40) put on 91 for the opening wicket and Martin Weightman (55), Oliver Tewatiya (31 not out) and Ross Whiteley (28) pushed the total along nicely.
Kiel Van Vollenhoven claimed figures of 3-30 from his seven overs.
Wollaton's reply got off to a sticky start and they were soon 32-3.
Van Vollenhoven (65) and Daniel Andrew (4) then dug in and put on 88 for the fourth wicket.
But two wickets apiece for Tewatiya, Alex King and George Scottorn helped restrict them to 180-8.
This Saturday Kimberley are at home to Plumtree, who have started the season well and sit joint top with Cavaliers & Carrington after winning three out of three.
Cavaliers were impressive 161-run winners away at Attenborough.
Kimberley’s second team beat visiting Anston by 34 runs in Division Two.
Choosing to bat, Kimberley made 228-9 in their 50 overs.
They struggled to get going and were 70-4.
But then Ross Carnall (46) and Joshua Bembridge (53) added 99 for the fifth wicket to push things along nicely. Buddika Karawgodalage (3-31) and Sam Taylor (3-39) took the bulk of the wickets.
In reply, Anston fell short at 194-9 with Joe Booker claiming 3-22 and Blayne Riley 3-53.